You may find these links of use:
For the record, I chose to buy my own ISBNs through Nielsen.
Although you will find that you can opt to get free ISBNs through many of the self-publishing services such as CreateSpace/KDP Print or Smashwords I would not recommend this. Why? Because the provider of the ISBN is shown as the publisher of record, and that won’t be you. In addition, if using a CreateSpace/KDP Print ISBN then it could alienate bricks and mortar bookshops when considering whether to stock your book because they know these are Amazon companies.
I go into more detail on ISBNs in How to Self-publish and Market a Children’s Book.